Ionization Energy:
The tendency of an atom to lose electrons & form a (+) ion.![]()
Ionization Energy is the energy required to remove 1 electron from a single atom in the gaseous state.
Electron Affinity: The tendency of an atom to gain electrons & form a (-) ion.
Electron Affinity is the energy released when an electron is added to a single atom in the gaseous state.
Example: Group IA elements (alkali metals) tend to lose 1 valence electron, thus forming ions with a +1 charge.
Alkali Metals therefore have:
1. Small ionization energies. Why? - Because their electrons are easily lost.
2. Small electron affinity. Why? - Because electrons electrons are not easily gained.
3. Net Result: Cation formation is favored.
Example: Group VIIA elements (the halogens) tend to gain 1 valence electron, thus forming ions with a -1charge.
Halogens therefore have:
1. Large ionization energies. Why? - Because their electrons are not easily lost.
2. Large electron affinity. Why? - Because they easily gain electrons.
3. Net Result: Anion formation is favored.